By David Fowkes on Monday, 26 October 2020
Category: Chemistry A Level

Entropy

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 Exothermic reactions always lead to an increase in entropy of the surroundings.  In an example like this - the burning of magnesium  in oxygen - the entropy of the system decreases  because a giant ionic lattice ( Magnesium Oxide) is formed from the magnesium metal and oxygen (gas). 

Energy profile for an exothermic reaction. 

Endothermic reactions can be spontaneous - so long as the entropy decrease of the surroundings  ( due to the reaction's positive enthalpy change is smaller than the entropy increase of the system

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